Balancing Chemical Equations

Set the coefficients on a real reaction and watch a live atom tally check both sides. Learn why every element must balance (conservation of mass) with steppers and a 'Show me' answer.

Written and reviewed by the PrepOK team Last reviewed How we check these lessons

A balanced equation obeys conservation of mass: atoms are only rearranged, never created or destroyed, so the count of every element must be the same on both sides. Change only the coefficients (the big numbers in front), never the subscripts inside a formula, until the tally matches.

1H₂1O₂1H₂O

The number in front is the coefficient: it multiplies the whole formula. The small numbers inside (subscripts) are part of the substance and never change.

Atom tally (from your coefficients)

ElementLeftRightMatch
H22
O21
Not balanced yet

Some element totals don't match (the red rows). Nudge the coefficients up or down so each row reads the same on the left and right.

Hydrogen and oxygen combine into water: two simpler substances forming one compound.

Tip: balance one element at a time, and leave free elements like oxygen or hydrogen until last. The smallest whole-number coefficients are the conventional answer.

Reaction types →·Stoichiometry →·Molecule Builder →

Formation of water, a synthesis reaction. Current atom tally: H: 2 on the left, 2 on the right; O: 2 on the left, 1 on the right (mismatch). Not yet balanced: adjust the coefficients so each element's totals match.

What balancing actually means

A chemical equation is a sentence written in formulas: reactants on the left, an arrow, and products on the right. Balancing it means choosing the numbers in front of each formula (the coefficients) so that every element appears the same number of times on both sides. The tool above lets you set those coefficients with − and + steppers and watch a live atom tally check your work, element by element. It is free to embed on your own site or LMS.

Why it has to balance: conservation of mass

Atoms are not created or destroyed in an ordinary chemical reaction; they are only rearranged into new combinations. This is the law of conservation of mass. If you start with two hydrogen atoms and one oxygen atom, you must end with exactly two hydrogen atoms and one oxygen atom; they have simply been reassembled into a water molecule. So when the count of an element differs between the two sides, the equation is describing an impossible reaction. The atom tally turns this rule into something you can see: each element gets a row, and a row that doesn’t match is flagged until you fix it.

Coefficients vs. subscripts

This is the distinction students trip on most. A subscript is part of the formula itself: the 2 in water (H₂O) says each molecule has two hydrogen atoms. You must never change it to balance an equation, because H₂O₂ is hydrogen peroxide, a different substance entirely. A coefficient is the number in front, and it multiplies the whole formula: 2 H₂O means two water molecules, or four H atoms and two O atoms in total. You balance an equation by adjusting coefficients only.

A worked example: burning methane

Take the combustion of methane, CH₄ + O₂ → CO₂ + H₂O. Start every coefficient at 1 and the tally is off: the left has 4 hydrogen atoms but the right has only 2, and oxygen doesn’t match either. Balance carbon first: one C on each side, so CH₄ and CO₂ are fine. Next hydrogen: 4 on the left, so put a 2 in front of water to get 2 H₂O, giving 4 H atoms on the right. Now count oxygen on the right: 2 from CO₂ plus 2 from 2 H₂O is 4, so put a 2 in front of O₂. The balanced equation is CH₄ + 2 O₂ → CO₂ + 2 H₂O: carbon, hydrogen, and oxygen all match. Try it in the tool, or hit Show me to reveal the answer for any reaction.

How to balance by inspection

For anything you will meet in a school course, this order works:

  1. Start with an element that appears in only one substance on each side. Carbon and hydrogen in a combustion reaction are usually the ones.
  2. Balance it by changing a coefficient, never a subscript.
  3. Move on to the next element, and expect earlier ones to go out of step. Fix them and keep going; it settles.
  4. Leave free elements until last. O₂, H₂, Cl₂ and the like appear on their own, so they can absorb whatever is left over without disturbing anything.
  5. Scale down at the end. If every coefficient shares a factor, divide it out: 4, 2, 4 is the same equation as 2, 1, 2, and the smaller set is the answer.

Take C₃H₈ + O₂ → CO₂ + H₂O. Carbon first: three on the left, so 3 CO₂. Hydrogen next: eight on the left, so 4 H₂O. That fixes the oxygen on the right at 6 + 4 = 10, and O₂ carries two atoms each, so 5 O₂. The answer is C₃H₈ + 5 O₂ → 3 CO₂ + 4 H₂O.

Balance your own equation

Pick Type your own equation in the menu above and write it the way you would on paper, like C3H8 + O2 -> CO2 + H2O. Any of ->, =, → will do as the arrow, coefficients are optional, and spaces do not matter.

The atom tally then works on your equation exactly as it does on the stored ones, so you can still balance it yourself with the steppers. Show me solves it, using linear algebra rather than trial and error: each element gives one equation and each substance is one unknown, so the coefficients are the smallest whole numbers that make every element cancel at once. That method does not care how awkward the equation is, which is why it handles 2 KMnO₄ + 16 HCl → 2 KCl + 2 MnCl₂ + 8 H₂O + 5 Cl₂ as easily as water.

One thing it will not do is guess at capital letters. co could be Co, cobalt, or CO, carbon monoxide, and those balance to different answers, so when a formula is ambiguous it asks instead of picking. When there is only one sensible reading it offers it back to you as a suggestion.

Balanced equations for 13 common reactions

The widget starts every coefficient at 1 on purpose, because working it out is the point. Here are the answers for when you want to check one.

13 common reactions written with their balanced coefficients, with the reaction type.
Reaction Balanced equation Type
Formation of water 2 H₂ + O₂ → 2 H₂O Synthesis
Haber process (ammonia) N₂ + 3 H₂ → 2 NH₃ Synthesis
Formation of table salt 2 Na + Cl₂ → 2 NaCl Synthesis
Burning magnesium 2 Mg + O₂ → 2 MgO Synthesis
Electrolysis of water 2 H₂O → 2 H₂ + O₂ Decomposition
Decomposition of limestone CaCO₃ → CaO + CO₂ Decomposition
Decomposition of hydrogen peroxide 2 H₂O₂ → 2 H₂O + O₂ Decomposition
Zinc in hydrochloric acid Zn + 2 HCl → ZnCl₂ + H₂ Single replacement
Iron in copper(II) sulfate Fe + CuSO₄ → FeSO₄ + Cu Single replacement
Silver nitrate + sodium chloride AgNO₃ + NaCl → AgCl + NaNO₃ Double replacement
Acid–base neutralization HCl + NaOH → NaCl + H₂O Double replacement
Burning methane CH₄ + 2 O₂ → CO₂ + 2 H₂O Combustion
Burning propane C₃H₈ + 5 O₂ → 3 CO₂ + 4 H₂O Combustion

Where balancing leads next

Once an equation is balanced, the coefficients become a recipe in moles: they tell you the ratio in which substances react and form. That ratio is the foundation of stoichiometry, where balanced equations let you predict how much product a reaction makes. The shape of the equation also reveals its category (synthesis, decomposition, replacement, or combustion) which you can explore in reaction types. And if you want to see the molecules behind the formulas, build them atom by atom in the Molecule Builder.

Frequently asked questions

What does it mean to balance a chemical equation?
Balancing means putting whole-number coefficients in front of each formula so that every element has the same number of atoms on the reactant side as on the product side. A balanced equation reflects the law of conservation of mass: atoms are only rearranged, never created or destroyed.
What is the difference between a coefficient and a subscript?
A coefficient is the big number in front of a formula and multiplies the whole formula: 2 H₂O means two water molecules. A subscript is the small number inside a formula that tells how many atoms of one element are in the substance, the 2 in H₂O. You balance equations by changing coefficients only; changing a subscript would turn it into a different substance.
Why can't I just change the subscripts to balance an equation?
Subscripts define what the substance is. Changing H₂O to H₂O₂ turns water into hydrogen peroxide, a completely different chemical. To keep the same substances and still balance the atoms, you may only adjust the coefficients in front.
Is there a trick for balancing equations?
A reliable approach: balance one element at a time, start with elements that appear in only one compound on each side, and save free elements like oxygen and hydrogen for last. Then scale all coefficients down to the smallest whole numbers.
Can I balance my own equation here?
Yes. Choose 'Type your own equation' in the reaction menu and write it like C3H8 + O2 -> CO2 + H2O. The atom tally works on whatever you type, so you can balance it yourself with the steppers, and 'Show me' solves it for you.
What is the balanced equation for propane burning?
C₃H₈ + 5 O₂ → 3 CO₂ + 4 H₂O. Balance carbon first (3 CO₂), then hydrogen (4 H₂O), which fixes the oxygen on the right at 6 + 4 = 10, so 5 O₂ on the left.
Why does my formula need capital letters?
Because chemistry is case sensitive and the meaning really changes. CO is carbon monoxide, one carbon and one oxygen; Co is cobalt, a single metal atom. Writing 'co' could mean either, so the tool asks rather than guessing.
Can an equation have more than one balanced answer?
Occasionally, yes. If two elements always appear in the same proportion across the substances, several different sets of coefficients balance the same equation, and it needs extra information to pin down. Most school equations have exactly one answer up to scaling.
How do you balance an equation with a polyatomic ion?
Treat the whole ion as a single unit whenever it survives the reaction unchanged. In Al + CuSO₄ → Al₂(SO₄)₃ + Cu, count sulfate as one thing rather than tracking sulfur and oxygen separately, and the answer 2, 3, 1, 3 comes out much faster.

Sources

The figures in this interactive are computed from unit-tested code and the sources above, not typed in by hand. See how we build and check these lessons, and tell us at support@prepok.com if you spot an error.

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